磷酸二氢钾溶液的pH对磷酸二氢钾产品质量及结晶特性的影响 - 202603 - 肥料与健康
磷酸二氢钾溶液的pH对磷酸二氢钾产品质量及结晶特性的影响
Effects of pH of Potassium Dihydrogen Phosphate Solution on Product Quality and Crystallization Characteristics of Potassium Dihydrogen Phosphate
doi: 10.3969/j.issn.2096-7047.2026.03.008
摘要:

为提升磷酸二氢钾产品质量,以某磷酸二氢钾装置生产的磷酸二氢钾溶液为研究对象,通过调节溶液的pH(4.0~5.6),结合热沉降、过滤、浓缩、结晶等步骤,开展了磷酸二氢钾溶液的pH对磷酸二氢钾产品中总养分含量、结晶量、杂质含量及晶体特性影响的试验。结果表明:磷酸二氢钾产品的总养分含量(KH2PO4的质量分数)随着磷酸二氢钾溶液的pH升高逐渐上升,当pH=4.80时,达到最大值,为98.07%,但结晶量显著下降;当pH=4.45时,结晶量达到最高,为141.40 g,但此时总养分含量最低,为91.17%;用氢氧化钾溶液调节至pH>5.00,可有效脱除磷酸二氢钾溶液中的钙、镁等离子,减少产品杂质。综合考虑产品质量与生产效率,建议工业生产中控制磷酸二氢钾溶液的pH为4.80~5.00,以平衡总养分含量与结晶量之间的矛盾,降低杂质含量。

关键词:
Abstract:

To improve the product quality of potassium dihydrogen phosphate, the potassium dihydrogen phosphate solution produced from a certain potassium dihydrogen phosphate unit is taken as the research object. By adjusting the pH of the solution (4.0-5.6) and combined with steps such as thermal settling, filtration, concentration, and crystallization, the effects of the pH of potassium dihydrogen phosphate solution on the total nutrient content, crystallization yield, impurity content, and crystal characteristics of the potassium dihydrogen phosphate product are experimented. The results show that with the increase of the pH of the potassium dihydrogen phosphate solution, the total nutrient content (mass fraction of KH2PO4) of the product gradually increases. When the pH reaches 4.80, the total nutrient content reaches a maximum of 98.07%, but the crystallization yield decreases significantly. At pH=4.45, the highest crystallization yield of 141.40 g is obtained, while the total nutrient content is at its minimum of 91.17%. Adjusting the pH to above 5.00 using potassium hydroxide solution is found to be effective in removing impurities such as calcium and magnesium ions from the solution, thereby reducing product impurities. Considering the balance between product quality and production efficiency, it is recommended that the pH of the potassium dihydrogen phosphate solution should be controlled between 4.80 and 5.00 in industrial production, so as to balance the contradiction between total nutrient content and crystallization yield, and to reduce impurity content.

Keyword:
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